PE hindered-amine halogen-free flame retardant masterbatchHALOGEN-FREE FR MASTERBATCH · PE films up to 15 silk (0.15 mm)
Built on hindered amines such as tetramethylpiperidine derivatives as the core flame-retardant component, compounded with a hindered-amine light stabiliser and LLDPE carrier resin — developed specifically for PE thin products up to 15 silk (0.15 mm), giving both flame retardancy and photo-oxidation resistance.
- Melt flow index MFI
- 0 g/10min
- Specific gravity
- 0 g/cm³
- Flame retardant rating
- UL94 V1 / V-2 (film grade)
- Processing temperature
- <0 ℃
Vertical burn: apply flame → remove and self-extinguish
Toggle the comparison: under the flame the specimen burns; after the flame is removed it self-extinguishes with a little residual smoke (UL94 V-2 film grade). The hindered amine traps free radicals and interrupts the chain reaction.
Hindered amine traps radicals · interrupts the chain reaction
The core hindered-amine structure traps free radicals during combustion and interrupts the chain reaction, achieving efficient extinguishing and flame suppression.
No chlorine or bromine · low smoke · no hydrogen halide
Contains no halogens such as chlorine or bromine; when burned it releases no toxic hydrogen halide gas, produces very little smoke, complies with RoHS and REACH, and suits sensitive applications such as food contact and electronic components.
Clarity and flexibility retained · FR + photo-oxidation resistance
Highly compatible with LDPE/LLDPE, does not bloom or exude, and does not noticeably affect film clarity, flexibility, hand feel or heat-sealing performance; compounded with a hindered-amine light-stabiliser system it delivers both flame retardancy and photo-oxidation resistance, slowing PE ageing.
Physical properties
A COA test report accompanies every batch.
Thickness limit · scope of application
Strictly limited to PE thin products up to 15 silk; the thinner the product (5–10 silk) the more the dosage should be raised.
All kinds of PE film
Packaging film, shrink film, protective film, agricultural greenhouse and mulch film, tent film and more.
Ultra-thin sheet and laminated film
Electronic insulation sheet, lightweight packaging sheet, cast film, coating products and more.
Monofilament and slit yarn
Woven yarn, drawn yarn and other thin fibre products with high flame-retardancy and toughness requirements.
Usage · precautions · sample request
Submit the form and a technical consultant will contact you within 24 hours to arrange a sample.
- Thickness limit: this product is only suitable for thin products up to 15 silk; flame retardancy in thick-walled structural parts will be affected.
- Formulation prohibitions and compatibility limits: never combine with flammable combustion-supporting ingredients (such as paraffin wax, esters, alumina, etc.); do not combine with anti-dripping agents, and it is not suitable for glass-fibre systems.
- Trial confirmation: if compounding with other additives or pigments is unavoidable, always run a small trial first and confirm there is no antagonistic reaction and that the flame-retardancy requirement is met before using it in production.
Usage and processing recommendations
01Product positioning
M911 belongs to the "functional masterbatch" category, with the official full name "PE Halogen-Free Flame Retardant Masterbatch M911", and its series affiliation is the functional masterbatch series. Manual table-of-contents line verbatim: "M911: PE Halogen-Free Flame Retardant Masterbatch — PE film halogen-free flame retardant, PE woven bag yarn halogen-free flame retardant (hindered amine type)"; official tagline line "PE film halogen-free flame retardant, PE woven bag yarn halogen-free flame retardant". (Data source: product handbook / official product data)
[Product Overview] verbatim: "PE halogen-free flame retardant masterbatch is compounded from hindered amine flame retardant, hindered amine light stabilizer, LLDPE resin, etc., subjected to high-efficiency dispersion processing, and pelletized. It can effectively provide flame retardancy and achieve good resistance to photo-oxidation. Mainly used in cast film, blown film, extrusion coating, drawing (yarn) and other products, with a significant effect on the fire and flame retardancy of the products." (Data source: product handbook / official product data)
This product is in finished masterbatch form: on the formulation side, "tetramethylpiperidine derivatives and other hindered amine types" serve as the core flame retardant component, compounded with hindered amine light stabilizer and LLDPE carrier resin; the official record states "M911 internally uses R911 PE halogen-free flame retardant" — the additive grade corresponding to the powder-side system is R911. (Data source: product handbook / official product data)
Thickness applicability threshold (official detail page): "only suitable for thin products within 15 si" "specifically developed for PE thin products within 15 si (0.15 mm)" — the manual body does not record this thickness boundary; the two are registered in parallel. (Data source: official product data)
- Halogen-free and eco-friendly — "contains no halogens such as chlorine or bromine, does not release toxic hydrogen halide gas when burning, has extremely low smoke output, complies with RoHS and REACH, and is suitable for sensitive scenarios such as food contact and electronic components".
- Flame retardant + photo-oxidation resistant dual effect — "can effectively provide flame retardancy and achieve good resistance to photo-oxidation"; the detail page records "flame retardant + photo-oxidation resistant dual effect, delaying PE aging".
- Film compatibility — "excellent compatibility with LDPE/LLDPE, not prone to migration, no blooming, and does not significantly affect film transparency, flexibility, hand feel, or heat-sealing performance".
- Masterbatch form — dry blending for direct processing, no powder dust; dispersion processing has already been completed at the pelletizing stage.
- Indicators can be re-tested — specific gravity 0.89 g/cm³, melt index 6.9 g/10min, accompanied by a COA test report supplied with each batch.
- Pre-use notice — "in the formulation, it is best not to use it together with flammable combustion-supporting components such as wax, ester, alumina, etc., nor with anti-dripping agents; it is not suitable for fiber reinforcement"; when it cannot be avoided, first conduct experiments to confirm compliance with product requirements before use.
02Formulation system & mechanism of action
Composition and process verbatim: "PE halogen-free flame retardant masterbatch is compounded from hindered amine flame retardant, hindered amine light stabilizer, LLDPE resin, etc., subjected to high-efficiency dispersion processing, and pelletized." Detail page composition statement: "tetramethylpiperidine derivatives and other hindered amine types as the core flame retardant component, compounded with hindered amine light stabilizer and LLDPE carrier resin". (Data source: product handbook / official product data)
Mechanism statement (detail page): "utilizes the core hindered amine structure to capture free radicals during combustion and interrupt the chain reaction, achieving efficient flame extinguishing and flame suppression." Data boundary: the manual's page for this grade does not elaborate the combustion mechanism and gives no LOI; the mechanism on this page follows the official detail page's wording, and does not fabricate or transplant the mechanism statement of other grades. (Data source: official product data)
Compliance statement (detail page): "contains no halogens such as chlorine or bromine, does not release toxic hydrogen halide gas when burning, has extremely low smoke output, complies with RoHS and REACH, and is suitable for sensitive scenarios such as food contact and electronic components." (Data source: official product data)
- Free Radical Capture — Hindered Amine Core StructureDuring combustion, the hindered amine structure captures free radicals and interrupts the chain reaction, achieving flame extinguishing and flame suppression (mechanism statement from the detail page).
- Photo-Oxidation Resistance — Compounded Hindered Amine Light StabilizerThe compounded hindered amine light stabilizer provides photo-oxidation resistance, "delaying PE aging" (dual-effect statement from the detail page).
- Carrier and Dispersion — LLDPE PelletizingLLDPE resin serves as the carrier, "high-efficiency dispersion processing, pelletized" — dispersion is completed at the pelletizing stage, ready for direct dry-blend use by the customer.
- Low Smoke Halogen-Free — Combustion PerformanceContains no halogens such as chlorine or bromine, does not release toxic hydrogen halide gas when burning, and has extremely low smoke output.
03Key parameters
The items recorded in the handbook specification table and the official product data are reproduced as follows (two forms of the flame-retardant rating are listed in parallel; the values in the table are as recorded in the source materials, and small-scale verification is recommended before bulk use).
| Item | Value / description |
|---|---|
| Main component | Hindered amine flame retardant, hindered amine light stabilizer, LLDPE resin |
| Addition ratio | 10% — 25% |
| Processing temperature | <250℃ (the handbook and the official field agree); the detail page recommends processing at 150–200℃ and avoiding decomposition at excessively high temperatures |
| Flame retardant performance | UL94 V-1 |
| Specific gravity | 0.89 g/cm³ |
| Melt index | 6.9 g/10min |
| Flame-retardant rating (film grade) | UL94 V1 / V-2 (film grade) — recorded in parallel with the "UL94V1" form in the handbook / field-level data |
| Appearance | Uniform plastic pellets |
| Applicable thickness threshold (detail page) | Only applicable to thin articles of 15 si (0.15 mm) or less |
| Documents supplied with the goods | A COA test report is supplied with each batch |
Reading notes: ① Two forms of the flame-retardant rating are listed in parallel — the handbook and the official field record "UL94V1", while the official detail page records "UL94 V1 / V-2 (film grade)"; the test specimen, thickness, testing organization and report number are all not stated in the source materials; ② The test conditions (temperature, load) for the melt index of 6.9 g/10min are not listed in the source materials; ③ No complete physical and chemical property table is attached for this grade (moisture content, melting point, decomposition temperature, etc. are not listed) — none is composed on our own; ④ The values in the table are as recorded in the source materials, and small-scale verification is recommended before bulk use. (Data source: product handbook / official product data)
04Recommended dosage window
Handbook specification table [Addition ratio]: 10%-25%. The denominator basis is the internal addition ratio — "for example, taking a 5% masterbatch addition: raw material 95% + masterbatch 5% = 100%". Thickness direction (official detail page): "the thinner the article (5–10 si), the more the addition ratio is recommended to be appropriately increased".
| Scenario | Dosage | Conditions & notes |
|---|---|---|
| PE system (internal addition) | 10% – 25% | Handbook specification table [Addition ratio]; denominator = total formulation (internal addition: raw material + masterbatch = 100%) |
| Thin articles (5–10 si) | Appropriately increase the addition ratio | Official detail page wording: "the thinner the article (5–10 si), the more the addition ratio is recommended to be appropriately increased"; the specific value is to be determined by small-scale trials |
The dosage direction is "the thinner the article, the higher the ratio" (official detail page); this may be opposite to the thickness direction of certain grades in the same series, and each grade follows its own source documentation and is not to be cross-applied. Ratio determination method (general rules): try several formulations and select the best; when the sample is only enough for one trial, use the highest recommended addition; for the first trial, do not add other fillers / additives; take several sample sections for testing. Measured application points (thickness × addition amount × rating) are not provided in the source materials, and this page does not extrapolate them.
To be verified: ① Measured points (thickness × addition amount → rating) are not provided in the source materials; ② The applicable conditions for the processing temperature upper limit <250℃ and the recommended range 150–200℃ (whether they relate to article thickness or process) are not explained in the source materials; ③ The above are values as recorded in the source materials; for actual production, please conduct small-scale trials in combination with your own PE grade and process to confirm.
05Applications
The official application list is "PE extrusion coating / PE film"; the official detail page gives three groups of applications, and the handbook's overview scenarios are cast film, blown film, extrusion coating and drawing — reproduced as follows.
- Various PE films
- Packaging film, shrink film, protective film, agricultural greenhouse film and mulch film, tent film, etc.
- Ultra-thin sheets and composite films
- Electronic insulating sheets, lightweight packaging sheets, cast film, extrusion-coated products, etc.
- Monofilament and flat filament
- Woven filament, drawn filament and other thin fiber products with relatively high requirements for flame retardancy and toughness.
- Handbook overview scenarios
- Cast film, blown film, extrusion coating, drawing.
- Feeding method
- Dry blending with PE pellets → blown film / cast film / extrusion.
- Combination limits (handbook precautions, verbatim)
- "In the formulation, it is best not to use it together with flammable combustion-supporting components, such as wax, esters, aluminum oxide, etc.; it also must not be used together with anti-drip agents, and is not suitable for fiber reinforcement. If such combination is unavoidable, first conduct experiments to confirm compliance with product requirements before use."
Field issues & application examples (as recorded in the source material)
| Field issue | What the source material states |
|---|---|
| Why is it called a "dual-effect" masterbatch? | A hindered amine light stabilizer is compounded on the component side: on the one hand, the hindered amine flame retardant imparts flame-retardant performance; on the other hand, it "can achieve good resistance to photo-oxidation" — the detail page records this as "flame retardant + photo-oxidation resistance, dual effect, delaying PE aging". |
| Can it be used for thick articles? | The official detail page gives a thickness threshold: "only applicable to thin articles of 15 si or less" and "specifically developed for PE thin articles of 15 si (0.15 mm) or less"; the handbook body does not state this boundary. For scenarios beyond this range, it is recommended to confirm with the supplier first. |
| What are the requirements for processing temperature and material drying? | Processing temperature: upper limit <250℃ ("the processing temperature must not exceed the maximum temperature recommended in the product introduction, otherwise the masterbatch performance will be damaged"), and the detail page recommends 150–200℃. The material drying clause follows the general rules: for the PE system, follow "after uniformly mixing the raw material and masterbatch, dry the material according to the original production process". |
| How should unused masterbatch be stored? | Follow the general moisture-proof clause: "Please seal and store the remaining unused masterbatch to prevent moisture from affecting the next use!" The packaging and storage clauses for this grade are not separately listed in the source materials; please request the accompanying documents for the specific material number. |
06How it differs from related grades
Comparison logic within the functional masterbatch series: first map by substrate — PE→M911 / PETG→M915 / PA6→M918 / PP→M933; then look at the flame retardant rating and processing conditions. The comparison is as follows:
| Grade | Substrate · Positioning | System | Addition ratio | Rating · Processing |
|---|---|---|---|---|
| M911 | PE · Halogen-free flame retardant masterbatch | Hindered amine flame retardant + hindered amine light stabilizer + LLDPE resin | 10%-25% (internal addition; the thinner the product (5–10 si), the higher the ratio) | UL94V1 (field level) / UL94 V1 / V-2 film grade (detail page); <250℃ |
| M915 | PETG · Transparent halogen-free flame retardant masterbatch | Phosphorus-nitrogen flame retardant + hyperdispersant + PETG resin (200 mesh filter) | 6%-10% | UL94 V-0; <280℃; specific gravity 1.21 g/cm³ |
| M918 | PA6 · Halogen-free flame retardant masterbatch | Phosphate + hyperdispersant + PA6 resin (350 mesh filter) | 8%-12% | UL94 V-0; <325℃; specific gravity 1.22 g/cm³; dripping type |
| M933 | PP · Halogen-free V0 flame retardant masterbatch | Phosphorus-based + a small amount of synergist (surface coating, PP carrier) | 15-25% (in application tests, a 0.4mm sheet at 25 parts drips without burning cotton) | High requirements at the high-temperature end; the data record that it satisfies halogen-free, melamine-free and sulfate-residue-free requirements |
| M922 | PP · Flame retardant masterbatch (low-halogen) | Phosphorus, nitrogen and bromine compound (antimony-free) | homopolymer 3.5% / blend 4%-6% / copolymer 8% | UL94 V2; specific gravity 1.10 g/cm³ |
Reading notes: ① The thickness-dosage direction of each grade follows that grade's own recorded convention — this grade has "the thinner, the higher the ratio", which is the opposite direction to some grades (e.g. M933 "the thinner the thickness, the smaller the addition ratio"); the two are listed as recorded and not applied to each other; ② M922 follows a low-halogen convention and is not described jointly with this product (halogen-free); ③ The values in each row come from that grade's own recorded data and are not cross-applied; ④ Choose between the masterbatch and the additive routes as needed: when a powder-end system is required, select the corresponding flame retardant grade (the additive grade corresponding to the PE system is R911). (Data source: product handbook / official product data)
07Usage & storage
The following points come item by item from the recorded data; items not listed in the data are not drafted on our own.
Dosage and ratio determination
- Internal addition ratio: 10%-25% (handbook specification table).
- Thin products (5–10 si): appropriately increase the addition ratio (per the official detail page).
- Ratio determination method (general provisions): try several formulations and select the best; for the first trial, do not add other auxiliaries / additives, and take several sample sections for testing.
Processing and use
- Processing temperature: upper limit <250℃ (must not be higher than the recommended maximum temperature, otherwise the masterbatch performance will be damaged); the detail page recommends 150–200℃.
- Feeding method: dry blend with PE pellets → blown film / cast film / extrusion.
- Material drying: for the PE system, follow "after uniformly stirring the raw material and the masterbatch, dry according to the original production process".
Moisture protection and accompanying documents
- Please keep the remaining unused masterbatch sealed to prevent moisture from affecting the next use.
- Each batch is accompanied by a COA test report.
Not stated in the data (not composed on this page)
- Packaging and shelf life, storage conditions (not listed separately on this grade's page; the governing convention is the moisture-protection clause in the general provisions); safety operation data (MSDS-type) entries —— please request the accompanying technical documents by specific item number.
08FAQ
Is M911 truly halogen-free?
Yes. The product name "PE halogen-free flame retardant masterbatch M911", the English name (Halogen-free) and the official detail page "contains no halogens such as chlorine and bromine" corroborate each other in three places; when burned it does not release toxic hydrogen halide gas, and the smoke volume is extremely low, meeting RoHS and REACH. (Data source: product handbook / official product data)
What is its relationship with R911?
The official record states "M911 internally uses R911 PE halogen-free flame retardant" —— M911 is the finished masterbatch form after pelletizing (dispersion is completed at the pelletizing stage, and the pellets have no powder dusting), while R911 is the powder-end additive grade; when a powder-end system is required, select the corresponding flame retardant grade.
How much is added?
Internal addition ratio 10%-25% (denominator = total formulation: raw material + masterbatch = 100%); for thin products (5–10 si) it is recommended to appropriately increase the addition ratio, with the specific value determined by a small-scale trial.
What should the processing temperature be controlled at?
Upper limit <250℃ —— "the processing temperature must not be higher than the maximum temperature recommended in the product introduction, otherwise the masterbatch performance will be damaged"; the detail page recommends processing at 150–200℃ and avoiding decomposition at excessively high temperatures.
Which additives cannot be combined?
Handbook precautions verbatim: "In the formulation it is best not to use it together with flammable and combustion-supporting components such as wax, esters, alumina, etc., and it must also not be used together with anti-dripping agents; it is not suitable for fiber reinforcement. If combination is unavoidable, first conduct experiments to confirm it meets the product requirements before use."
What is the flame retardant rating?
Two forms are listed side by side: the handbook and the official field record "UL94V1"; the official detail page records "UL94 V1 / V-2 (film grade)". The test specimen, thickness, testing organization and report number are not stated in the data; this page presents them side by side without selecting one.
AppendixData sources
The data on this page come from two types of sources and are traceable item by item:
- Product handbook: the catalogue line, specification table and general provisions of the masterbatch booklet in which this grade appears (the denominator convention for the addition ratio, the general provisions on processing temperature, the material-drying and moisture-protection clauses, and the precautions).
- Official product data: all fields of this grade (name, category, slogan, description, mechanism, application, parameters, main components, addition ratio); the functional masterbatch series entry; the official detail page copy and FAQ.
Not covered by the source material (not written on this page — to be added later)
- The halogen-free determination threshold (halogen content at ppm level) and the third-party test report number —— the data only contain the statement "contains no halogens such as chlorine and bromine".
- The relationship between the two forms of the UL94 rating: the test specimen, thickness, testing organization and report number are all absent from the data.
- The test conditions (temperature, load) for the melt index of 6.9 g/10min are not listed in the data.
- The applicable conditions for the upper processing temperature limit of <250℃ and the recommended range of 150–200℃ are not explained in the data.
- Quantitative mechanical and film performance data (tensile and impact retention; light transmittance, haze) and the oxygen index (LOI) —— not provided in the data.
- Missing items in the complete physicochemical specifications: moisture content, melting point, decomposition temperature, etc. (no specification table is attached for this grade).
- The specific grade of the "LLDPE carrier resin" and the specific chemical names and proportions of the hindered amine flame retardant and light stabilizer —— not stated in the data.
- The determination method and basis for the 15 si thickness threshold —— given on the official detail page, not stated in the body of the handbook.
- Packaging and shelf life, storage conditions —— not listed on this grade's page, and not drafted on our own.