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Making dispersion more efficient.

Functional masterbatch series

TECHNICAL DATA SHEET · TDS-M922 · REV 2026-09 · CN

PP flame retardant masterbatchPP FLAME RETARDANT MASTERBATCH · P·N·Br antimony-free system

Finely processed from our own flame retardant R912, a phosphorus–nitrogen–bromine compound system, free of antimony and fully RoHS compliant. Dual solid-phase plus gas-phase synergy with catalytic melt-drip heat removal extinguishes the flame efficiently.

P-N-Br synergistic flame retardancyAntimony-free / RoHS compliantDual solid-phase and gas-phase synergyHigh gloss / no exudation / low density
SPECIMEN · M922White cylindrical pellets
Active flame retardant content
0 %
Flame retardant rating
UL94 V2
Decomposition temperature TGA1%
0 ℃
MFI (200℃,5kg)
0 g/min
Melting point ≥160℃ · moisture ≤0.1% · RoHS
0%
Active flame retardant content
UL94V2
Flame retardant rating
0℃
Decomposition temperature TGA1%
0g/cm³
Density · low
SEC.01 / SYNERGY & DRIP

P·N·Br synergy · catalytic melt-drip heat removal and self-extinguishing

Top: the P·N·Br three-node synergy pulse. Bottom: after the flame is removed in the vertical burn test the catalytic melt drips away carrying heat, and the flame self-extinguishes (UL94 V2).

Catalytic melt drips away carrying heat · rapid self-extinguishing · low smoke
SYNERGY / dual synergy

P·N·Br synergy + catalytic melt-drip heat removal

Using the synergy of phosphorus, nitrogen and bromine together with a catalytic melt-drip heat-removal mechanism (which accelerates melt dripping of the resin and quickly carries heat away), it achieves rapid self-extinguishing and highly efficient flame retardancy.

GREEN / antimony-free, low corrosion

Antimony-free · RoHS · low smoke

Contains no antimony (Antimony-free) and is fully RoHS compliant; when burned it produces little smoke and is minimally corrosive to processing moulds and equipment.

QUALITY / no exudation · high gloss

Low density · no long-term blooming

Light in density and highly compatible, it does not exude or bloom in long-term use and keeps the surface of the part highly glossy; good melt fluidity, easy processing and a strong cost advantage (compared with the conventional octa-bromo system).

SEC.02 / SPECIFICATION

Physicochemical properties and indices

A COA test report accompanies every batch.

ItemValue
AppearanceWhite cylindrical pellets
Flame retardant ratingUL94 V2
Active flame retardant content25%
Environmental standardRoHS
Density1.10 g/cm³
Moisture content≤ 0.1%
Melting point≥ 160 ℃
Melt flow index MFI15 g/min (200℃,5kg)
Decomposition temperature (TGA1%)230 ℃
Flame retardant systemP·N·Br compound (antimony-free)
SEC.03 / VS OCTA-BROMO

Compared with the conventional octa-bromo system · six items, lower is better

Shorter bar is better: M922 is lower than the conventional octa-bromo system on all six items — halogen, antimony, density, exudation, smoke and mould corrosion.

M922 vs conventional octa-bromo system · six comparisons (shorter is better)
Conventional octa-bromo systemM922
Halogen content
Antimony content
Density
Exudation / blooming
Smoke generation
Mould corrosion
PP corrugated pipe

Conduit, corrugated pipe and other construction and industrial pipes.

PP hollow sheet

All kinds of flame-retardant packing board, hollow partitions and more.

Fibre and film

PP flame-retardant filament, staple fibre, packaging film and more.

Moulded parts

Electrical appliance housings, automotive parts and various engineering moulded parts.

SEC.04 / DOSAGE & CONTACT

Recommended dosage · packing and storage · sample request

Select the dosage according to the PP matrix type; submit the form and we will respond with a sample within 24 hours.

Recommended dosage (by PP matrix type · 0 – 10% scale)
Homopolymer PP
3.5%
Homopolymer / copolymer PP blend
4% – 6%
Copolymer PP
8%

Packing and storage

Packing25 kg / bag · double PE moisture-barrier liner
Storage adviceCool, dry and ventilated · sealed · moisture-proof · avoid direct sunlight
Flame retardant systemP·N·Br compound (antimony-free)
Environmental standardRoHS · Antimony-free

Request an M922 sample

Free sample · PP flame-retardant formulation guidance · reply within 24 hours

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01Product positioning

M922 belongs to the functional masterbatch category; its Chinese name is "PP Flame Retardant Masterbatch M922"; the handbook table-of-contents line, verbatim: "M922: PP low-halogen flame-retardant masterbatch — PP corrugated pipes, hollow sheets, spinning, films, injection molding". The official English positioning line, verbatim: "Low-halogen flame-retardant PP masterbatch for corrugated pipes, hollow sheets, spinning, films and injection molding." — This product is a "low-halogen" masterbatch (phosphorus, nitrogen and bromine compound system, containing bromine); the page describes it under a low-halogen framing and makes no "halogen-free"-type claims. (Data source: product handbook / official product data)

System self-description, verbatim: "M922 masterbatch is processed from our company's self-produced flame retardant R912; it is a flame retardant of the phosphorus, nitrogen and bromine compound system, antimony-free, and complies with the ROHS standard." (This sentence is the source's own wording; this page reproduces it verbatim and does not extrapolate the properties of other grades.) (Data source: product handbook / official product data)

Mechanism, verbatim: "Its flame-retardant mechanism is a dual solid-phase and gas-phase synergy that improves flame-retardant efficiency, supplemented by an appropriate catalytic reaction that accelerates resin dripping and rapidly carries heat away, thereby achieving a highly efficient flame-retardant effect." The page labels the mechanism as "solid phase + gas phase dual synergy + catalytic melt-drip heat removal". (Data source: product handbook / official product data)

Comparison with conventional systems (source, verbatim): "Compared with conventional octabromodiphenyl ether system masterbatches, M922 features low halogen content, no antimony, low specific gravity, no migration, low smoke emission and low mold corrosiveness; the product has high gloss and is easy to process." The page summarizes the differences as six comparison items: halogen content / antimony content / specific gravity / migration·blooming / smoke emission / mold corrosion. (Data source: product handbook / official product data)

  • Low-halogen system — phosphorus, nitrogen and bromine compound (containing bromine); "low halogen content" relative to conventional octabromodiphenyl ether systems; antimony-free, RoHS compliant.
  • Six comparison items (relative to conventional octabromodiphenyl ether systems) — low halogen content, antimony-free, low specific gravity, no migration / no blooming, low smoke emission, low mold corrosiveness.
  • Processing performance (as stated on the page) — high surface gloss of the finished article, good melt flow, easy processing; extremely low corrosiveness to processing molds and equipment.
  • Application breakdown (page) — PP corrugated pipes (conduit and other construction and industrial pipes); PP hollow sheets (flame-retardant packaging boards, hollow partitions, etc.); spinning and films (PP flame-retardant filament, staple fiber, packaging film, etc.); injection-molded articles (electronic and electrical plastic housings, automotive parts and various engineering injection-molded parts).
  • Three dosage levels — homopolymer PP 3.5% / homopolymer-copolymer blend systems 4%–6% / copolymer PP 8%.
  • Documents shipped with the goods — the page states "a COA test report is enclosed with each batch".

02Formulation system & mechanism of action

System: a phosphorus, nitrogen and bromine compound flame-retardant system (the source states it is processed from a self-produced flame retardant), antimony-free — antimony is a synergist metal, not a halogen, so "antimony-free" and the halogen tier are two independent matters: this product's halogen direction is described as "low halogen content" (relative to conventional octabromodiphenyl ether systems). (Data source: product handbook / official product data)

Flame-retardant mechanism: a dual solid-phase and gas-phase synergy that improves flame-retardant efficiency; supplemented by an appropriate catalytic reaction that accelerates resin dripping and rapidly carries heat away, thereby achieving a highly efficient flame-retardant effect. The page labels the mechanism as "solid phase + gas phase dual synergy + catalytic melt-drip heat removal". (Data source: product handbook / official product data)

The six-item summary of differences from conventional systems is given in section 1; the page additionally notes of this product "contains no heavy-metal antimony, RoHS compliant", "low smoke emission, extremely low corrosiveness to processing molds and equipment", "low specific gravity, good compatibility, no migration or blooming in long-term use, high surface gloss of the finished article, good melt flow, easy processing". The source gives no ppm-level measured values of halogen content, and gives no oxygen index (LOI) or quantitative mechanical data — this page does not supply them on the source's behalf. (Data source: product handbook / official product data)

  1. Solid phase + gas phase dual synergySource mechanism sentence: "The flame-retardant mechanism is a dual solid-phase and gas-phase synergy that improves flame-retardant efficiency."
  2. Catalytic dripping heat removal"Supplemented by an appropriate catalytic reaction that accelerates resin dripping and rapidly carries heat away, thereby achieving a highly efficient flame-retardant effect."
  3. Internal addition into the systemAdded according to the masterbatch's "internal addition ratio" general rule (the denominator being the total mass of the resin system); good compatibility with PP systems, no migration or blooming in long-term use.
  4. Three dosage levelsSelect the level by PP type: homopolymer 3.5%, homopolymer-copolymer blend 4%–6%, copolymer 8%; the flame-retardant rating is recorded in the source as UL94 V2 (no separate rating is given per level).

03Key parameters

The product specifications recorded in the product handbook and official product data are as follows. The values in the table are as recorded in the documentation; before bulk use, it is recommended to run a small-scale trial with your own PP system to confirm.

Table 1 · PP Flame Retardant Masterbatch — key parameters
ItemValue / description
Main componentManufactured from our self-produced flame retardant R912; a phosphorus-nitrogen-bromine compound system flame retardant; antimony-free
AppearanceWhite cylindrical pellets
Environmental standardROHS
Flame retardant ratingUL94V2
Effective flame retardant content25
Density (g/cm³)1.10
Moisture content (%)≤0.1
Melting point (℃)≥160
Melt index (g/min,200℃ 5kg)15
Decomposition temperature (℃ TGA1%)230
SystemPhosphorus, nitrogen and bromine combined system (low-halogen direction); antimony-free, RoHS compliant
Mechanism noteSolid-phase + gas-phase dual synergy + catalytic melt-drip heat removal
Maximum processing temperatureNot listed for this entry (other flame retardant masterbatches in the same series all list it); the general rules require "must not exceed the maximum temperature recommended in the product introduction sheet"
Storage recommendationCool, dry and ventilated · sealed · moisture-proof · avoid direct sunlight (the documentation also notes that a COA test report is supplied with each batch)
Effective flame retardant content25
Density (g/cm³)1.10
Moisture content (%)≤0.1
Melting point (℃)≥160
Melt index (g/min,200℃ 5kg)15
Decomposition temperature (℃ TGA1%)230

Reading notes: (1) "effective flame retardant content 25" — the handbook specification table gives no unit, while the official product data records 25%; the two are shown side by side; (2) no oxygen index (LOI) data is recorded for this grade; (3) another column header in the specification table is an undefined internal code, not used on this page and not replaced with a fabricated value; (4) the masterbatch concentration is a property of the masterbatch itself and is a separate matter from the end-use addition ratio. (Data source: product handbook / official product data)

effective flame-retardant content25/ 100
Effective flame-retardant content 25 (25 of 100 squares) · 25

04Recommended dosage window

The dosage is divided into three tiers by PP type (verbatim from the documentation); the denominator follows the masterbatch series' "internal addition ratio" convention — total mass of the resin system (example from the general rules: raw material 95% + masterbatch 5% = 100%).

Table 2 · M922 — recommended dosage
ScenarioDosageConditions & notes
Homopolymer PP (Homopolymer)3.5%Identical wording in the handbook and official product data (internal addition ratio, denominator = total mass of the resin system)
Homopolymer / copolymer PP blend system4% – 6%Same as above
Copolymer PP (Copolymer)8%Same as above; the documentation gives only one flame retardant rating, UL94 V2 (no separate rating is given per tier)

Trial dosage method (general rules for masterbatches): it is recommended to try several formulations to select the most suitable addition ratio; if the sample is only enough for one trial, use the highest recommended dosage; for a first trial, do not add other auxiliaries or additives at first, and add them gradually after a successful trial; when testing, take several sample sections for measurement. It is also recorded that "trial results vary; production equipment, process temperature, product formulation and other factors all affect the result — please run more trials, adjust the process, and patiently experiment to choose the optimal solution".

M922 three dosage tiers (by PP type)
Figure 1 · M922 three dosage tiers: homopolymer 3.5% / homopolymer-copolymer blend 4%–6% / copolymer 8% (horizontal axis is internal addition ratio / %; denominator = total mass of the resin system). Data source: product handbook and official product data; the values in the figure match the table above item by item.

To be verified: (1) the tiering rationale for the three dosages (3.5% / 4-6% / 8%) and the corresponding product thickness conditions; (2) the maximum processing temperature for this grade is not listed; (3) the test thickness, specimen preparation and testing organization for UL94 V2; (4) all of the above are values recorded in the documentation; the actual formulation should be determined by small-sample testing.

homopolymer PP3.5%3.5%7homopolymer-copolymer blend4%6%4-6%12copolymer PP8%8%16
Dosage levels by PP type (1 particle = 0.5%) · 3.5% · 4-6% · 8%

05Applications

The official application list is PP corrugated pipe, PP hollow board, chemical fiber, PP film, injection molding; the page's application breakdown is given item by item below.

PP corrugated pipe
Conduit pipes, corrugated pipes and other construction and industrial pipes (page application breakdown).
PP hollow board
Flame retardant packaging boards, hollow partition boards, etc. (page application breakdown).
Spinning and film
Flame retardant PP filament, staple fiber, packaging film, etc. (page application breakdown); the official application list includes chemical fiber.
Injection molded parts
Plastic housings for electrical and electronic appliances, automotive parts and various engineering injection molded parts (page application breakdown).
Compatibility note
The page records "low specific gravity, good compatibility, no migration in long-term use, no blooming"; the documentation does not provide a separate compatibility matrix entry.
Alignment with general rules for masterbatch use
Drying is required before trial (the drying list in the general rules covers PET / PA6 / PETG / PU / TPU, etc., not including PP; follow the original production process); the processing temperature must not exceed the maximum temperature recommended in the documentation; keep the remaining unused masterbatch sealed and protected from moisture.

Field issues & application examples (as recorded in the source material)

Table 4 · Application case highlights
Field issueWhat the source material states
Is M922 a halogen-free product?No. This product is a "halogenated · low-halogen" system: a phosphorus, nitrogen and bromine combination (contains bromine), described as "low halogen content" relative to the traditional octabromodiphenyl ether system. The page describes it in low-halogen terms and makes no "halogen-free" type claims. If a halogen-free system is needed, please select separately from the halogen-free grade catalogue.
Are "antimony-free" and "halogen-free" the same thing?No. Antimony is a synergist metal, not a halogen — "antimony-free" means the system contains no heavy metal antimony and is RoHS compliant; the halogen tier is a separate matter, and this product is in the low-halogen direction.
What is the dosage?Three tiers by PP type: homopolymer 3.5%; homopolymer / copolymer blend 4%–6%; copolymer 8%. The denominator is the total mass of the resin system (internal addition ratio convention).
How does it differ from traditional flame retardant systems?Six items from the documentation: low halogen content, antimony-free, low specific gravity, no migration (no blooming), low smoke generation, low mold corrosion; the page also records high surface gloss of the finished article, good melt flow and easy processing.

06How it differs from related grades

On the functional masterbatch side, lines are divided by substrate; this table gives the coordinates of this grade together with the boundaries of adjacent grades in the same series (the comparison columns are the original text of each respective document, and the values are not transferred between them).

Table 5 · Comparison with related grades
DimensionM922 (this grade)M933 (PP halogen-free direction)
Substrate / systemPP; P-N-Br compound (low-halogen direction, antimony-free)PP; phosphorus-based + a small amount of synergist (surface coating, PP carrier), meets halogen-free requirements
Addition ratiohomopolymer 3.5% / blend 4%–6% / copolymer 8%15-25% (the thinner the thickness, the smaller the addition ratio)
Flame retardant ratingUL94 V2The documentation records that when 25 parts are added to 0.4mm PP sheet, the drips do not ignite cotton; meets halogen-free, melamine-free, and sulfate-residue-free
Halogen tierHalogenated · low-halogen (no halogen-free claims are made)Halogen-free direction
Thickness directionNot listed in the documentation (no direction clause is given for this grade)The thinner the thickness, the more it is reduced

Reading notes: (1) The two grades differ in halogen tier (low-halogen vs halogen-free direction) — choose a side according to compliance requirements; neither replaces the other; (2) The numerical basis for the addition ratio differs, so do not substitute one for the other; (3) The thickness-direction clause is independent for each grade (no direction is given for this grade). (4) The comparison columns are the original text of each respective document. (Data source: product handbook / official product data)

07Usage & storage

The following points are taken item by item from the documented records (including the general instructions for using the masterbatch series).

Processing and dosage

  • Three dosage tiers: homopolymer 3.5% / homopolymer/copolymer blend 4%–6% / copolymer 8% (internal addition ratio, with the denominator being the total mass of the resin system).
  • Processing temperature: must not exceed the recommended maximum temperature in the product brochure, otherwise the masterbatch performance will be degraded (no upper limit is listed in the entry for this grade; refer to the technical documents supplied with the goods).
  • Test-sample results are affected by equipment, process temperature, formulation, and other factors — the documentation recommends running more test samples and adjusting the process to select the optimal solution.

Packaging and storage

  • Packaging: 25 kg / bag, double-layer PE bag (official record: "25 kg/bag · lined with a double-layer PE moisture-proof bag").
  • Storage recommendations: cool, dry, and ventilated · sealed · moisture-proof · away from direct sunlight.
  • Store leftover unused masterbatch in a sealed state to prevent moisture from affecting the next use.

Documents supplied with the goods

  • A COA test report is supplied with each batch (as noted on the page).

Not documented (not written on this page)

  • Measured halogen content at the ppm level and the third-party test report number — the documentation gives only the qualitative statement "low halogen content".
  • Oxygen index (LOI) data and quantified mechanical property data (tensile / impact retention, etc.) — not provided in the documentation.
  • The threshold and test method for determining "low-halogen" — not provided in the documentation (only a qualitative statement).
  • Shelf life — not provided in the documentation (the page gives storage recommendations but no shelf-life item).

08FAQ

How should M922's halogen tier be described?

According to the documentation: this product is a P-N-Br compound system (contains bromine), with "low halogen content" relative to the traditional octabromodiphenyl ether system — that is, the low-halogen direction. No halogen-free claims are made on this page; "antimony-free" is a separate matter (antimony is a synergist metal, not a halogen).

How do you choose among the three dosage tiers?

By PP type: homopolymer PP 3.5%; homopolymer / copolymer blend system 4%–6%; copolymer PP 8%. The denominator is the total mass of the resin system; it is recommended to try several formulations and select the most suitable addition ratio.

What is its flame retardant mechanism?

Dual solid-phase and gas-phase synergy improves flame retardant efficiency; in addition, an appropriate catalytic reaction accelerates resin dripping, rapidly carrying away heat. The page labels the mechanism as "solid-phase + gas-phase dual synergy + catalytic melt-drip heat removal".

Is it equipment-friendly during processing?

The page states "minimal corrosiveness to processing molds and equipment", "good melt fluidity, easy to process", and "high surface gloss of the finished product"; relative to traditional systems, it offers low mold corrosion, no exudation, and no blooming. Quantified data is not provided in the documentation.

Packaging, storage, and shelf life?

Packaging 25 kg / bag (double-layer PE bag, lined with a double-layer PE moisture-proof bag); storage recommendations: cool, dry, and ventilated, sealed, moisture-proof, away from direct sunlight; store leftover masterbatch sealed to prevent moisture. Shelf life is not provided in the documentation.

AppendixData sources

The data on this page comes from two types of documents, each traceable item by item:

  • Product handbook: the full entry for this grade (title / overview / physicochemical properties / application fields / product specifications / packaging); the general instructions for the masterbatch series (material drying, hard requirements on processing temperature, definition of the internal addition ratio, trial-dosage method, moisture-proof storage); the comparison entry and catalog line for the same series.
  • Official product data: all fields for this grade (name, category, positioning, description, mechanism, application, specifications, main components, dosage); page-level copy (positioning line, six-item comparison, application breakdown, dosage basis, packaging and storage, COA notes).

Not covered by the source material (not written on this page — to be added later)

  • Measured halogen content at the ppm level and the third-party test report number; the threshold and test method for determining "low-halogen" — not provided in the documentation.
  • The specific name and proportion of the bromine-containing component; its compounding relationship with the flame retardant source grade self-described in the documentation — not elaborated in the documentation.
  • The unit and conversion basis for "effective flame retardant content 25" — the handbook does not specify a unit, while the official record states 25%, and the two are listed side by side.
  • Upper limit of processing temperature, oxygen index (LOI), quantified mechanical data, UL94 V2 test details, shelf life — not listed in the documentation.
  • The tiering rationale for the three dosage tiers and the corresponding article thickness conditions — not provided in the documentation.

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