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Making dispersion more efficient.

General additives series

TECHNICAL DATA SHEET · TDS-R77F · REV 2026-09 · CN

Breathable water and oil repellentContains no perfluorinated or organofluorine compounds; passes PFAS testing.Internal addition · biomimetic lotus effect · breathable water and oil protection

Added internally to chemical fibre products, it lowers the fibre surface tension so that water droplets cannot wet the surface — this process is called water and oil repellency, also known as breathable water and oil protection; the fabric still keeps good breathability.

  • 🍃 Biomimetic lotus · droplets roll off and self-clean
  • ✅ PF compliant (passes perfluorinated-substance testing)
  • 🧵 Resists washing · dry cleaning · rubbing · durable
  • 💨 Does not affect the original breathability
FABRIC CROSS-SECTIONRepellent · yet breathable
Specific surface area
0 ± 25 m²/g
Bulk density (approx.)
≈ 0 g/l
pH (4% dispersion)
0 – 0
Appearance
White powder
0–0%
Recommended dosage in the final product
0±25m²/g
Specific surface area
>0Wt.%
SiO₂ (on ignited basis)
0kg
Bag packing
SEC.01 / CORE FEATURES

Core product features · the threefold lotus effect

Compliance, biomimicry and durability — the three promises of internal-addition water and oil repellency.

COMPLIANCE / PF compliance

Passes perfluorinated-substance testing

Although it contains fluoride ions, it is completely free of per- and polyfluorinated organic compounds (organic fluorine pollution sources such as PFOA / PFOS), so it passes all stringent perfluorinated-substance tests smoothly, combining high performance with ecological compliance.

BIOMIMICRY / lotus effect

Droplets bead up and slide off fast

It gives chemical fibre and plastic surfaces very high hydrophobic and oleophobic performance, so droplets form lotus-like beads that slide off quickly, delivering an outstanding anti-soiling, self-cleaning experience.

DURABILITY / durable by internal addition

Wash · dry-clean · rub resistant

As an internal-addition modifier, the active ingredient blends deeply into the substrate and resists washing, dry cleaning and rubbing, while not affecting the original breathability of the fabric.

Overview: R77F is added internally to chemical fibre products to lower the fibre surface tension so that water droplets cannot wet the surface; it suits raincoats, shell jackets, travel bags, protective wear and similar materials. The water and oil repellency of a fabric also depends on the fabric structure; fabric treated with R77F still keeps good breathability; it can also be used for anti-soiling plastic film and various anti-soiling plastic parts.

SEC.02 / COMPOSITION & SPEC

Main components · physical and chemical indices

The three composition segments are stacked in their true proportions; the indices are typical ex-works values.

Hydrogenated silicone 56%Silica SiO₂ 27.5%Magnesium oxide MgO 16.5%
Test itemSpecification
AppearanceWhite powder
Specific surface area230 ± 25 m²/g
Bulk density (approximate)approx. 330 g/l
pH value (in 4% dispersion)4.2 – 5.8
Moisture content (2 hours at 105℃)< 3 Wt.%
SiO₂ content (based on ignited material)> 28 Wt.%
Loss on ignition< 72 Wt.% (material dried for 2 hours at 105℃, ignited for 2 hours at 1000℃)
SEC.03 / DOSAGE & APPLICATION

Dosage and application areas

A low dosage of 0.8–1%; two main battlegrounds — chemical fibre textiles and anti-soiling plastics.

Recommended dosage

0.8% — 1%
Final plastics compound (0–1% scale)
TEXTILE / chemical fibre textiles

Raincoat · shell jacket · travel bag · protective wear

RaincoatShell jacketTravel bagProtective wear
PLASTICS / plastic products

Anti-soiling film · anti-soiling parts · injection-moulded parts

Anti-soiling plastic filmAnti-soiling plastic partsInjection-moulded parts
SEC.04 / PACKAGE & CONTACT

Packing and storage · sample request

Submit the form on the right and a technical consultant will contact you within 24 hours to arrange a sample.

Packing and storage

Packing10 kg / bag
StorageStore in a cool, dry place · keep away from moisture
AppearanceWhite powder
ComplianceFree of PFOA / PFOS · passes perfluorinated-substance testing

Request an R77F sample

Free sample · water and oil repellent formulation guidance · reply within 24 hours

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01Product positioning

R77F is a processing aid (plastic internal-additive-type breathable water- and oil-repellent agent), not a masterbatch: a white powder, three-component, added directly into chemical fiber and plastic raw material systems. The manual page title reads verbatim "Breathable water- and oil-repellent agent R77F", while the table-of-contents line and the official full name read verbatim "Plastic internal-additive-type breathable water- and oil-repellent agent R77F"; the website list title and detail page title read "Hydrophobic agent (containing fluoride ions)" and "Plastic internal-additive-type hydrophobic agent (containing fluoride ions)". The naming at each level coexists; this page records them layer by layer without altering one another. (Data source: product handbook / official product data)

Main components verbatim: "Silicon dioxide 27.5% hydrogenated silicone 56% magnesium oxide 16.5%" — the three items written adjacent to one another, totaling 100%. As for the role of magnesium oxide (16.5%) in this product, the materials give no functional description (the entire source has only one mention, the ingredient table); this page states only the compositional facts and makes no mechanistic inference. (Data source: product handbook / official product data)

Overview verbatim (main mechanism line): "The process of adding the breathable water- and oil-repellent agent R77F internally into chemical fiber products to lower the surface tension of the fibers, so that water droplets cannot wet the surface, is called water and oil repellency, also known as breathable waterproof and oil-proof. It is suitable for materials such as raincoats, shell jackets, travel bags and protective clothing. The water- and oil-repellent effect of the fabric is also related to the fabric's structural organization. Fabric to which the R77F water- and oil-repellent agent has been added can still maintain its breathability. Because it is an internal-additive-type water- and oil-repellent agent, it has excellent resistance to washing, dry cleaning and rubbing, as well as breathability and durability, etc. It can also be used for anti-fouling plastic films and various anti-fouling plastic components, etc." (Data source: product handbook / official product data)

Separate note on the fluorine position (specific to this product): the official data layer registers it as "containing fluoride ions (contains no perfluorinated or organofluorine compounds, can pass perfluorinated checks)"; the compliance narrative follows the perfluorinated-compliance direction — this product does not belong to a halogen-free system, and the page writes no compliance statements in the halogen direction. This grade does not involve flame retardancy, and there is no flame-retardant rating or flame-retardant mechanism. (Data source: official product data)

  • Definition of water and oil repellency (source text) — "the process of lowering the surface tension of the fibers, so that water droplets cannot wet the surface, is called water and oil repellency, also known as breathable waterproof and oil-proof".
  • Breathability retention — "fabric to which the R77F water- and oil-repellent agent has been added can still maintain its breathability"; the page wording is "does not affect the fabric's original breathability performance".
  • Durability chain — "excellent resistance to washing, dry cleaning and rubbing, as well as breathability and durability, etc."; the page wording is internal-additive-type modification, with the active ingredients deeply fused with the substrate.
  • Perfluorinated compliance (official wording, verbatim) — "containing fluoride ions (contains no perfluorinated or organofluorine compounds, can pass perfluorinated checks)"; the official data/list layer uses "perfluorinated checks" and the page layer uses "perfluorinated testing", recorded layer by layer as written.
  • Application examples — materials such as raincoats, shell jackets, travel bags and protective clothing; also "anti-fouling plastic films, various anti-fouling plastic components, etc.".
  • Conditional statement on effect — "the water- and oil-repellent effect of the fabric is also related to the fabric's structural organization": the effect results from the combined action of the additive and the structural organization.

02Formulation system & mechanism of action

Composition facts: white powder, three-component formulation — silicon dioxide 27.5%, hydrogenated silicone 56%, magnesium oxide 16.5% (totaling 100%). The materials give no role annotations or compatibility explanations for each component; this page does not presume to assign roles. (Data source: product handbook / official product data)

The action route is internal addition: the additive enters the interior of the chemical fiber system, lowering the fiber surface tension so that water droplets cannot wet the surface — this is the source's definition of "water and oil repellency = breathable waterproof and oil-proof". Because it comes from internal modification of the system rather than a surface coating, the water-repellency durability chain (resistance to washing, dry cleaning and rubbing, breathability, durability) holds together with "still maintaining breathability". (Data source: product handbook / official product data)

The three feature cards on the page layer (qualitative statements, not measured data): (1) eco-friendly perfluorinated compliance — "although it contains fluoride ion components, it is completely free of perfluorinated and organofluorine compounds (such as PFOA / PFOS and other organofluorine pollution sources), and can smoothly pass all stringent perfluorinated testing indicators"; (2) biomimetic lotus-leaf effect — water beads form round droplets on the surface and quickly roll off, providing anti-fouling self-cleaning; (3) internal addition for high durability — resistance to washing, dry cleaning and rubbing, without affecting the fabric's original breathability performance. Quantitative criteria such as contact angle values, water-repellency ratings, durability cycle counts and retention rates are not given in the materials, and this page does not cite them as measured data. (Data source: official product data)

  1. Internal addition — entering the chemical fiber systemAdded in the internal-additive manner into chemical fiber products (fabrics) or plastic systems; the specific process steps, mixing equipment and parameters are not given in the materials, and this page does not presume to draft them.
  2. Lowering surface tension — water droplets cannot wetLowers the surface tension of the fibers, so that water droplets cannot wet the surface — this is the source's definition of water and oil repellency (breathable waterproof and oil-proof).
  3. Breathability retention — fabric structure stays unblockedThe fabric after addition can still maintain its breathability; the page wording is "water vapor passes through freely · breathability retained".
  4. Durability performance — resistance to washing / dry cleaning / rubbingThe durability chain brought by the internal-additive route: resistance to washing, dry cleaning and rubbing, breathability, durability; the page wording is deep fusion of the active ingredients with the substrate.

03Key parameters

The physicochemical specifications recorded in the product handbook and official product data are as follows (the in-page wording and ordering of the specifications follow each page's original form, transcribed as-is by layer and not mutually altered). The values in the table are those recorded in the source materials; before bulk use, it is recommended to carry out small-scale trials with your own system.

Table 1 · Breathable Hydrophobic R77F — key parameters
ItemValue / description
Main componentSilicon dioxide 27.5% hydrogenated silicone 56% magnesium oxide 16.5%
AppearanceWhite powder
Bulk density(approximate value) approx. 330g/l
Specific surface area230+25M2/g
Water contentAt 105℃ for 2 hours’ <3Wt.%
Loss on ignitionMaterial dried at 105℃ for 2 hours, then ignited at 1000℃ for 2 hours <72Wt%
PH value4.2-5.8 in a 4% dispersion
SIO contentBased on the ignited material Wt.% >28
Component categoryThree-component system: silicon dioxide, hydrogenated silicone, magnesium oxide (the source gives percentages but no annotation of each component's role)
Fluorine basis (official registration)Contains fluoride ions (contains no perfluorinated or organofluorine compounds; can pass perfluoro inspection)
Halogen directionNot applicable (this product does not belong to a halogen-free system; the page states no halogen-direction compliance wording)

Reading notes: (1) The specific surface area is written on the handbook page as "230+25M2/g" ("M2" is the in-page original notation); (2) The loss on ignition is written on the handbook page as "<72Wt%"; (3) The specification pages' wording and ordering follow each page's original form and are not mutually overwritten or unified with other model pages; (4) The role of magnesium oxide in this product is not explained in the source materials. (Data source: product handbook / official product data)

04Recommended dosage window

The dosage uses a single basis: the denominator is the plastic final product (as stated in the source), range 0.8%—1%; the handbook, the official dosage field, and the page presentation are consistent in all three places. The source gives no breakdown by substrate or scenario.

Table 2 · R77F — recommended dosage
ScenarioDosageConditions & notes
Addition to the plastic final product0.8% — 1%The handbook's [Addition level] and the official dosage field use the same wording (denominator: plastic final product); the page scale is noted as "plastic final product (0–1% scale)"
Substrate breakdownNot recorded in the source materialsThe source gives only the overall range and does not break it down by substrate/scenario; this page does not draft one.
Effect conditionsRelated to fabric structure"The water- and oil-repellent effect of the fabric is also related to the fabric's structure" — the effect results from the combined action of the additive and the fabric structure.

Denominator note: this model has only one denominator basis — the plastic final product; the source gives no substrate breakdown. Thickness-direction clause: none for this model (a full-source search for "thickness / thinner" returns no record relating to this model); this page uses no directional wording and does not apply the directional clauses of other models.

R77F reference dosage window (as a proportion of the plastic final product)
Figure 1 · R77F reference dosage window: 0.8% – 1% (mass fraction of the plastic final product / %). Data source: product handbook and official product data; the values in the figure are consistent item by item with the table above.

To be verified: (1) Dosage breakdown details and upper-limit verification — the source gives only the overall range "0.8%—1% of the plastic final product", and none is drafted here. (2) Processing details (process steps, mixing equipment requirements, feeding order) are not given in the source. (3) The quantitative criteria for the "lotus effect / hydrophobic and oleophobic" behavior and durability (contact angle, water-repellency grade, wash / dry-clean / abrasion cycles and retention rate) are not given in the source. (4) All of the above are values recorded in the source materials; for actual production, please conduct small-scale trials in combination with the fabric structure and process.

05Applications

The application examples given in the source overview and the official application field (breathable functional film, protective clothing fabric, breathable packaging) are itemized as follows; this model's page has no separate [Application scope] subsection, and this page does not fill one in.

Breathable functional film / breathable packaging
Listed in the official application field; the page scenarios include anti-fouling plastic film.
Protective clothing fabric
Application examples in the overview: "raincoats, shell jackets, travel bags, protective clothing and other materials"; the official application field includes protective clothing fabric.
Raincoats / shell jackets / travel bags
Listed verbatim among the application examples in the overview.
Anti-fouling plastic film and anti-fouling plastic parts
"Can also be used for anti-fouling plastic film, various anti-fouling plastic parts, etc."; the page scenarios additionally list injection-molded parts.
Breathability retention (application condition)
"Fabrics to which the R77F water- and oil-repellent agent has been added still retain their breathability"; the effect is related to the fabric structure.
Boundary note
This product has the opposite direction from R77 (R77 is a fluorine-free system, while this product follows the fluorine-ion direction) — the two form a paired set of pages, are not interchangeable, and their values are not cross-applied; no code-by-code correspondence with the masterbatch-side models is recorded for this product, and dosages are not cross-calculated.

Field issues & application examples (as recorded in the source material)

Table 4 · Application case highlights
Field issueWhat the source material states
Will water and oil repellency also block breathability?The source points out breathability retention in two places: "Fabrics to which the R77F water- and oil-repellent agent has been added still retain their breathability"; "also called breathable waterproof and oil-proof". The page states that it "does not affect the fabric's original breathability".
Does containing fluorine make it non-environmentally friendly?Official position: this product contains fluoride ions, but "contains no perfluorinated or organofluorine compounds (such as PFOA / PFOS and other organofluorine pollution sources)" and can pass perfluoro inspection. The compliance theme is the perfluoro compliance direction; this product does not belong to a halogen-free system, and the page states no halogen-direction wording.
How to choose between this and R77?Choose sides by fluorine direction: R77F follows the fluorine-ion direction (this model), while R77 is a fluorine-free system; the two directions are opposite and they are not interchangeable. The source gives no scenario-by-scenario either/or rule; it is recommended to confirm by small-scale trials according to end-use compliance requirements and the fabric structure.
What role does the 16.5% magnesium oxide play?Not explained in the source materials. A full-source search shows that "magnesium oxide" appears for this product in only one place, the composition table, with no functional description and no compatibility explanation — this page makes no functional inference and records only the compositional fact.

06How it differs from related grades

R77F and R77 are paired page for page, opposite in direction; they differ in fluorine direction, number of components, specification values, and dosage. The comparison is as follows (for demarcation only, not an equivalence comparison):

Table 5 · Comparison with related grades
DimensionR77F (this grade)R77 (reference)
Official full name · CategoryPlastic internal-additive breathable water- and oil-repellent agent R77F · breathable water repellentPlastic internal-additive water- and oil-repellent agent R77 · water and oil repellent
Fluorine directionFluorine-containing ions (free of perfluorinated and organofluorine compounds; can pass perfluorinated checks)Fluorine-free system (purely fluorine-free system)
Main componentsSilicon dioxide 27.5% + hydrogenated silicone 56% + magnesium oxide 16.5% (ternary)Silicon dioxide 33% + hydrogenated silicone 67% (binary)
Key specificationsSpecific surface area 230+25M2/g; bulk density approx. 330g/l; pH (4% dispersion) 4.2-5.8; SIO content >28 Wt.%; loss on ignition <72Wt%Specific surface area 200+25m²/g; bulk density approx. 320g/l; pH 4.5-6.2; Sio content >33; loss on ignition <66Wt.%
Addition content0.8%—1% of the final plastic product0.5%—1% of the final plastic product
Packaging10 kg/bag10kg/bag

Reading notes: (1) The two grades are identical only in two items—appearance and moisture content (white powder / moisture content <3Wt.%); the rest are differences as written on their respective pages; (2) The dosage values differ (0.8%—1% vs 0.5%—1%) and must not be cross-used; (3) The compliance positions on the pages are independent of each other (this grade's side is perfluorinated compliance; R77's side is fluorine-free and environmentally friendly) and are not interchangeable; (4) This table serves for demarcation only and is not an equivalence comparison of performance. (Data source: product handbook / official product data)

07Usage & storage

The following points are taken item by item from documented sources; items not listed in the sources are not drafted on our own initiative (this product belongs to the additive line and does not follow the general series rules of the masterbatch side).

Addition method

  • Added internally to chemical fiber products (handbook wording); the form field is "internal-additive type".
  • Specific process steps (mixing equipment, screw / spinning parameters, feeding sequence) are not provided in the sources—not drafted on our own initiative.
  • Effect conditions: the water- and oil-repellent effect of the fabric is also related to the fabric's structure.

Dosage and basis

  • Addition content: 0.8%—1% of the final plastic product (identical wording in the handbook and the official field).
  • Single denominator (the final plastic product), with no substrate-based tiers; no thickness-dosage direction clause.

Packaging and storage

  • Packaging: 10 kg/bag.
  • Storage conditions: a cool, dry place (the page adds "store · protect from moisture").

Not stated in the sources (not compiled on this page)

  • Compatibility entries are entirely absent (statements on compatibility with the matrix, chemical fiber systems, and other processing additives are not listed on this grade's page).
  • Processing temperature window, shelf life, safety data (MSDS-type), and handling protection entries—none are recorded in the sources.
  • The methods and reports for perfluorinated detection (testing organization / indicators) and statements of compliance with environmental regulations (RoHS / REACH, etc.)—are not attached in the sources.

08FAQ

Are R77F and R77 different grades of the same product?

No. The two are independent grades: separate pages, separate data entries, separate category fields (R77F is a "breathable water repellent"; R77 is a "water and oil repellent"), opposite in direction and not interchangeable.

Should the addition amount be 0.8%—1% or 0.5%—1%?

For this grade: 0.8%—1% of the final plastic product (consistent in the handbook, the official dosage field, and the page—three places). 0.5%—1% is R77's value; the two grades have different values and are not cross-used.

Which wording is correct, "perfluorinated check" or "perfluorinated detection"?

The two wordings belong to two official levels: the official data / list level writes "perfluorinated check", while the page level writes "perfluorinated detection". They are transcribed by level and not unified on our own; the meaning is the same, both referring to this product's ability to pass the relevant perfluorinated item checks.

What is the difference between internal addition and external coating?

This product is of the internal-additive type: the additive enters the interior of the system and lowers the fiber surface tension; the sources record its "excellent resistance to washing, dry cleaning, and rubbing, its breathability, and its durability", and that "the fabric can still retain its breathability". The sources do not provide experimental control data against external coating.

Which fabrics is it suitable for? What determines the effect?

Overview examples: materials such as raincoats, shell jackets, travel bags, and protective clothing; the official application field: breathable functional films, protective clothing fabrics, and breathable packaging. The sources state explicitly that "the water- and oil-repellent effect of the fabric is also related to the fabric's structure".

What are the packaging and storage conditions?

Packaging is 10 kg/bag; storage conditions are a cool, dry place (the page adds a note to protect from moisture). The sources do not record shelf life, and this page does not draft it on its own.

AppendixData sources

The data on this page come from two types of sources and are traceable item by item:

  • Product handbook: the entire technical data page of this grade (title / overview / main components / physicochemical specifications / packaging / storage conditions); the technical data page with identical wording in the comprehensive series booklet (mutual corroboration between the two booklets); the list sentence in the company introduction (written in the same sentence as R77).
  • Official product data: all fields of this grade (name, category, positioning, description, mechanism, application, physicochemical parameters, main components, recommended dosage, packaging, storage); the official website list headings and page-level copy (including three feature cards on perfluorinated compliance, bionic lotus-leaf effect, and internal-additive high durability).

Not covered by the source material (not written on this page — to be added later)

  • The role and compatibility mechanism of magnesium oxide (MgO) 16.5%—not explained in the sources.
  • Compatibility entries, processing details, processing temperature window, shelf life, and MSDS-level safety data—not listed in the sources.
  • Quantitative criteria for the lotus-leaf effect and durability (contact angle values, water-repellency rating, number of washing / dry-cleaning / rubbing cycles and retention rates)—not provided in the sources.
  • The scenario-by-scenario selection boundary between R77 and R77F, and the code-by-code correspondence with the masterbatch-side grades—not stated in the sources.
  • The methods and reports for perfluorinated detection and statements of compliance with environmental regulations—not attached in the sources.

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